In order to solve the problems of roof breakage, support difficulty, water and mud inrush encountered in underground space operations such as mining and tunnel excavation, polyester ammonia/water glass organic-inorganic hybrid grouting reinforcement material was taken as the research object. By establishing a similar simulation grouting model, the temperature and pressure of measuring points at different distances from the injection point during the model grouting process were studied, and the slurry diffusion law was analyzed. The mechanical properties of grouting reinforcement were analyzed to test the consolidation effect. The results show that the polyurethane(PU)/water glass double-liquid grouting material exhibits irregular diffusion in the broken rock test model, and the curing reaction is an exothermic reaction. It reaches a maximum of 83.2 ℃ at 10 min after slurry injection, which is 6.6 times of room temperature. The maximum pressure is 5.7 MPa, which is 1.425 times of the test load. The temperature and pressure increase rapidly with time and then slowly decline and finally stabilize. The uniaxial compressive strength range of polyurethane/water glass double liquid grouting and solid is 15.32 ~ 32.57 MPa, the maximum bearing capacity of triaxial loading is 41.9 MPa, the residual strength is 25 MPa, the maximum load of creep failure is 25 MPa, and the strength of the injected material is greatly improved after consolidation. Through the microscopic analysis of grouting reinforcement, it can be seen that the rock and slurry are closely cemented at the junction, and the grouting reinforcement effect is good.