基于热力学过程的二氧化碳管道泄漏速率高精度计算方法

杨明 ,  陈晓玲 ,  尚妍 ,  焦健 ,  邢晓凯

科学技术与工程 ›› 2025, Vol. 25 ›› Issue (29) :12586-12592

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科学技术与工程 ›› 2025, Vol. 25 ›› Issue (29) :12586-12592 DOI: 10.12404/j.issn.1671-1815.2407483
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基于热力学过程的二氧化碳管道泄漏速率高精度计算方法

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High-precision Calculation Method for Leakage Rate of Carbon Dioxide Pipelines Based on Thermodynamic Processes

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摘要

管道输送CO2作为碳捕集、利用与封存(carbon capture, utilization, and storage, CCUS)技术的中间纽带,对CCUS系统的运行起到至关重要的作用。而泄漏是CO2管输过程中的主要风险,其中泄漏速率是评估管道泄漏事故的关键指标。由于泄漏过程涉及压力和物性的剧烈变化,仿真方法往往难以收敛。同时经典小孔泄漏对于CO2管道泄漏的计算精度无法满足实际需求。为解决这一问题,提出了一种基于等熵膨胀过程和壅塞效应的数学模型,考虑缩脉效应对泄漏的影响,对泄漏口流通面积进行修正。该模型可用于CO2管道泄漏口的温度、压力和泄漏速率的准确计算,其预测结果与泄漏实验数据吻合良好,表现出较高的计算精度和稳定性,显著优于经典小孔泄漏模型。该模型可为泄漏远场扩散的研究提供泄漏源强数据,进而为CO2管输安全工程方面的决策提供参考。

Abstract

The pipeline transportation of CO2 plays a crucial role in carbon capture, utilization, and storage (CCUS) systems as an intermediate link. Leakage is the primary risk in CO2 pipeline transportation process, with the leakage rate being a key indicator for assessing pipeline leakage incidents. Due to the significant variations in pressure and thermophysical properties during the leakage process, simulation methods often face convergence difficulties. Moreover, the classical small-orifice leakage model fails to meet the accuracy requirements for CO2 pipeline leakage calculations. To address this issue, a mathematical model based on isentropic expansion and choked flow effects was proposed. The effect of vena contracta on leakage was considered, and the flow area at the leakage orifice was modified. This model allows for accurate calculation of the temperature, pressure, and leakage rate at the CO2 pipeline leak, with the predicted results aligning well with experimental leakage data, demonstrating high computational accuracy and stability, significantly outperforming classical small-orifice leakage models. This model can provide leakage source strength data for research on far-field leakage dispersion, thereby offering a valuable reference for decision-making in CO2 pipeline transportation safety engineering.

关键词

CCUS / 二氧化碳 / 泄漏速率 / 计算模型

Key words

CCUS / carbon dioxide / leakage rate / calculation model

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杨明, 陈晓玲, 尚妍, 焦健, 邢晓凯. 基于热力学过程的二氧化碳管道泄漏速率高精度计算方法[J]. 科学技术与工程, 2025, 25(29): 12586-12592 DOI:10.12404/j.issn.1671-1815.2407483
YANG Ming, CHEN Xiao-ling, SHANG Yan, JIAO Jian, XING Xiao-kai. High-precision Calculation Method for Leakage Rate of Carbon Dioxide Pipelines Based on Thermodynamic Processes[J]. Science Technology and Engineering, 2025, 25(29): 12586-12592 DOI:10.12404/j.issn.1671-1815.2407483

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基金资助

新疆维吾尔自治区天山创新团队(2022TSYCTD0002)

克拉玛依市创新环境建设(创新人才)项目(2024hjcxrc0057)

新疆维吾尔自治区“一事一议”引进战略人才项目(XQZX20240054)

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