桂北中奥陶统升坪组页岩元素地球化学特征及其地质意义

吴海东 ,  余烨 ,  王莉 ,  刘泽华

科学技术与工程 ›› 2025, Vol. 25 ›› Issue (8) :3110-3122

PDF (21896KB)
科学技术与工程 ›› 2025, Vol. 25 ›› Issue (8) :3110-3122 DOI: 10.12404/j.issn.1671-1815.2403855
天文学、地球科学

桂北中奥陶统升坪组页岩元素地球化学特征及其地质意义

作者信息 +

Element Geochemistry Characteristics and Geological Significance of Middle Ordovician Shengping Formation Shale in Northern Guangxi

Author information +
文章历史 +

摘要

为了研究桂北中奥陶统升坪组黑色页岩的形成机理、形成区的古环境和古气候、构造背景和物源等,在广西壮族自治区桂林市全州县文桥镇栗水村溪水源剖面升坪组采集16件黑色页岩以及黑色硅质页岩样品,并对其进行元素地球化学测试和分析。结果表明:溪水源剖面升坪组黑色页岩中主量元素SiO2的含量最高(62.37% ~ 91.65%,平均值为78.04%),其次为Al2O3(2.88% ~ 16.92%,平均值为9.15%),研究区微量元素与北美页岩(NASC)的含量相比所有元素均表现为亏损。样品(La/Yb) N值为7.185 ~ 15.858,平均值为10.678,轻稀土元素(LREE)/重稀土元素(HREE)为8.165 ~ 15.440,平均值为11.029。表明轻重稀土分异现象较明显,LREE相对HREE富集;δEu值表现负异常(0.589 ~ 0.950,平均值为0.758);δCe值表现正异常(1.165 ~1.412,平均值为1.259)。地球化学特征显示:溪水源剖面升坪组黑色页岩源区构造背景为被动大陆边缘,源岩类型为沉积岩;源区遭受了中等偏强程度的化学风化,受化学风化作用影响较大,以温湿气候为主;沉积环境以缺氧的还原环境为主。

Abstract

In order to study the formation mechanism, paleoenvironment, paleoclimate, tectonic background, and source of black shale in the Shengping Formation of the Middle Ordovician in northern Guangxi, sixteen samples of black shale and black siliceous shale were collected from the Shengping Formation at Xishuiyuan section in Quanzhou County, Guilin City, Guangxi Zhuang Autonomous Region, and element geochemistry testing and analysis were conducted on them. The results show that the content of the main element SiO2 in the black shale of the Shengping Formation at Xishuiyuan section is the highest (62.37% ~ 91.65%, average 78.04%), followed by Al2O3(2.88% ~16.92%, average 9.15%). Compared with the North American shale (NASC), the content of trace elements in the study area shows a loss for all elements. The value of the sample (La/Yb)N is 7.185 ~ 15.858, with an average of 10.678. The light rare earth elements (LREE)/heavy rare earth elements (HREE) values are 8.165 ~ 15.440, with an average of 11.029. It indicates that the differentiation phenomenon of light and heavy rare earth elements is more obvious, and LREE are relatively enriched compared to HREE. The δEu value exhibits negative anomalies (0.589 ~ 0.950, with an average value of 0.758); The δCe value exhibits positive anomalies (1.165 ~ 1.412, with an average of 1.259). The geochemical characteristics show that the structural background of the black shale source area in the Shengping Formation of the Xishuiyuan profile is passive continental margin, and the source rock type is sedimentary rock. The source area has undergone moderate to strong chemical weathering, which is greatly affected by chemical weathering, with a predominantly warm and humid climate. The sedimentary environment is mainly a deoxidizing environment with oxygen deficiency.

关键词

黑色页岩 / 沉积环境 / 地球化学 / 升坪组 / 桂北地区

Key words

black shale / sedimentary environment / geochemistry / Shengping Formation / northern Guangxi region

引用本文

引用格式 ▾
吴海东, 余烨, 王莉, 刘泽华. 桂北中奥陶统升坪组页岩元素地球化学特征及其地质意义[J]. 科学技术与工程, 2025, 25(8): 3110-3122 DOI:10.12404/j.issn.1671-1815.2403855
WU Hai-dong, YU Ye, WANG Li, LIU Ze-hua. Element Geochemistry Characteristics and Geological Significance of Middle Ordovician Shengping Formation Shale in Northern Guangxi[J]. Science Technology and Engineering, 2025, 25(8): 3110-3122 DOI:10.12404/j.issn.1671-1815.2403855

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

基金资助

湖南省自然科学基金(2023JJ30239)

湖南省教育厅资助科研项目(23B0467)

PDF (21896KB)

36

访问

0

被引

详细

导航
相关文章

/

〈 〉