
科学技术与工程

中国技术经济学会
生化法处理城市污水一氧化二氮排放综述
Review of Biochemical Treatment of N2O Emissions from Urban Wastewater
“双碳”背景下,污水处理不仅要实现资源化,还要减少碳排放。为降低N2O排放,中外学者对城镇污水厂N2O排放开展了大量研究。首先,概述污水处理中硝化过程和反硝化过程都会产生N2O,反应过程中产生N2O机理与方式也存在差异,N2O的产生量也会由于工艺不同而改变。其次,综述3种典型污水生物脱氮工艺:循环式活性污泥法(cyclic activated sludge system, CASS)工艺、厌氧氨氧化(anaerobic ammonium oxidation, ANAMMOX)工艺、亚硝化-厌氧氨氧化(nitrosation anaerobic ammonium oxidation, CANON)工艺,以及影响城镇污水厂N2O排放量产生的4种因素:碳源、溶解氧浓度、温度、磁场强度。最后,总结目前研究尚存在的不足,并从温度影响条件、碳源种类、CANON工艺机理、N2O回收利用4个方面进行展望。CANON工艺对于去除N2O有较好的效果,但需注意,反应中PH过低使NH2OH和HNO2反应生成N2O,从而削弱去除效果。
Under the background of "dual carbon", sewage treatment not only needs to achieve resource utilization, but also needs to reduce carbon emissions. To reduce N2O emissions, scholars at home and abroad have conducted extensive research on N2O emissions from urban sewage plants. Firstly, it was summarized that both nitrification and denitrification processes in wastewater treatment produce N2O. The mechanism and mode of N2O production during the reaction process also differ, and the amount of N2O produced may vary depending on the process. Secondly, three typical biological denitrification processes for wastewater were reviewed: cyclic activated sludge system (CASS) process, anaerobic ammonium oxidation (ANAMMOX) process, and nitrosation anaerobic ammonium oxidation (CANON) process, as well as four factors affecting N2O emissions from urban wastewater treatment plants: carbon source, dissolved oxygen concentration, temperature, and magnetic field strength. Finally, the shortcomings of current research were summarized and provided prospects from four aspects: temperature influencing conditions, carbon source types, CANON process mechanisms, and N2O recovery and utilization. The CANON process is effective for removing N2O, but it should be noted that a low pH in the reaction can cause NH2OH and HNO2 to react and produce N2O, thereby weakening the removal effect.
dual carbon / nitrification / N2O / denitrification / carbon source
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