氨水强化超临界二氧化碳地质埋存方法

师少桓 ,  陈文滨 ,  王硕亮 ,  蒋珊

科学技术与工程 ›› 2024, Vol. 24 ›› Issue (31) :13335-13341

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科学技术与工程 ›› 2024, Vol. 24 ›› Issue (31) :13335-13341 DOI: 10.12404/j.issn.1671-1815.2307642
石油、天然气工业

氨水强化超临界二氧化碳地质埋存方法

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Ammonia Water Enhanced Geological Storage of Supercritical Carbon Dioxide

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摘要

为提高二氧化碳捕集、利用与封存(CO2 capture, utilization and storage, CCUS)末期CO2地质埋存能力,提出氨水强化CO2埋存方法,向储层注入氨水,利用氨水与CO2发生化学反应提高CO2埋存量。通过高温高压物理模拟装置和岩心驱替装置,选定实验参数范围为20 MPa、40 ~ 80 ℃、氨水浓度6% ~ 26%,选取高渗岩心进行实验,明确了氨水与CO2的反应规律和岩心中氨水强化CO2埋存效果。结果表明,氨水吸收CO2的量与氨水浓度呈正比,与温度呈反比,但低温会析出碳酸氢铵晶体,减少氨水吸收CO2的量;氨的吸收能力与氨水浓度呈负相关,与温度没有明显的线性相关性;在60 ℃条件下,6%浓度的氨水表现出最佳的CO2吸收效果;与饱和地层水相比,饱和6%浓度氨水可使岩心的CO2埋存量提高7.5倍;岩心迂曲度每增加0.5,氨水强化埋存的单位岩石孔隙体积CO2埋存量可以增加200 mL,而地层水埋存的单位岩石孔隙体积CO2埋存量仅增加11 mL。该研究首次提出了一种新的二氧化碳埋存模式并开展实验研究,为CCUS项目强化二氧化碳地质埋存提供了一种新思路和新途径。

Abstract

In the advanced phase of CCUS(CO2 capture, utilization and storage), a technique for increasing the CO2 geological storage capacity using ammonia water was suggested. Ammonia water was injected into the reservoir, where it reacted with CO2 to expand the storage volume. A high-temperature, high-pressure physical simulation device and core flooding apparatus was utilized to narrow down the experimental parameters for 20 MPa, 40 ~ 80 ℃, and an ammonia water concentration of 6% ~ 26%. The interaction between ammonia and CO2 and ammonia's efficacy in amplifying CO2 storage were clarified through the experiments. The results show that the amount of CO2 absorbed by ammonia is proportional to the concentration of ammonia, and inversely proportional to the temperature. But ammonium bicarbonate crystals will be precipitated at low temperature, reducing the amount of CO2 absorbed by ammonia. The absorption capacity of ammonia is negatively correlated with ammonia concentration, but had no obvious linear correlation with temperature. Saturated 6% ammonia water increases the CO2 storage volume in cores by 7.5 times compared to saturated formation water. Moreover, with every 0.5 increase in core tortuosity, the CO2 storage volume per unit rock pore volume in ammonia-enhanced storage increases by 200 mL, whereas that in formation water storage only rises by 11 mL. An innovative CO2 storage model and conducts experimental research is presented for the first time, which provid a new approach and method for enhancing CO2 geological storage in oil and gas field CCUS projects.

关键词

CCUS / CO2地质埋存 / 氨水 / 化学反应 / 迂曲度

Key words

CCUS / CO2 geological storage / ammonia water / chemical reaction / tortuosity

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师少桓, 陈文滨, 王硕亮, 蒋珊. 氨水强化超临界二氧化碳地质埋存方法[J]. 科学技术与工程, 2024, 24(31): 13335-13341 DOI:10.12404/j.issn.1671-1815.2307642
SHI Shao-huan, CHEN Wen-bin, WANG Shuo-liang, JIANG Shan. Ammonia Water Enhanced Geological Storage of Supercritical Carbon Dioxide[J]. Science Technology and Engineering, 2024, 24(31): 13335-13341 DOI:10.12404/j.issn.1671-1815.2307642

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基金资助

国家自然科学基金(52374051)

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