渝东南含铝岩系元素迁移富集规律及成矿过程
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1.重庆市地质矿产勘查开发局107地质队;2.中国地质大学(武汉)地球与行星科学学院

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P595,P612

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重庆市技术创新与应用发展专项重点项目(CSTB2024TIAD-KPX0097);重庆市规划和自然资源局科研项目(KJ-2025032);重庆市地质矿产勘查开发局重大科研项目(DKJ-2024-107/607-B-001);


Element Migration and Enrichment Patterns and Mineralization Process of Bauxite in Southeastern Chongqing
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107 Geological Team, Chongqing Bureau of Geology and Mineral Resources Exploration and Development;2..School of Earth and Planetary Sciences, China University of Geosciences (Wuhan)

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    摘要:

    渝东南地区含铝岩系赋存于二叠系中统梁山组,经历了“成矿母岩→黏土岩→铝土岩→铝土矿”的多阶段风化—成矿演化过程。本文基于钻孔岩芯样品的XRD、XRF、ICP-MS测试结果,结合CIA、ICV等风化指标及Grant质量平衡方程与Isocon图解,系统分析了该区元素迁移富集规律与成矿机制。结果表明,研究区风化强度总体极高,CIA由灰岩阶段迅速升高并在铝土矿阶段接近100,指示成矿体系经历了强烈化学风化与持续淋滤作用。元素迁移表现出显著阶段性:红土化阶段以Ca、Sr、Ba等碳酸盐相关元素强烈亏损及Al、Si相对富集为特征;脱硅富铝阶段以SiO2深度流失、Al2O3显著富集及Li等关键金属富集为主;纯化富集阶段则表现为杂质元素进一步淋失、Al相对纯化以及Ga、V、Cr等伴生元素的富集。相关性分析表明,Li主要受黏土矿物控制,Ga主要以类质同象替代进入铝矿物晶格,REE则受铁锰氧化物、黏土矿物及风化—成岩环境共同控制。研究认为,渝东南铝土矿成矿本质上是极端湿热气候下,碳酸盐岩溶蚀、黏土化、脱硅富铝及成岩纯化共同驱动的结果,为该区铝土矿及伴生关键金属的成矿预测与资源评价提供了地球化学依据。

    Abstract:

    The aluminum-bearing rock series in southeastern Chongqing occurs above the Huanglong Formation limestone and has undergone a multistage weathering–mineralization evolution from “ore-forming parent rock→ claystone → bauxite rock → bauxite ore.” Based on XRD, XRF, and ICP-MS analyses of drill-core samples, together with weathering indices such as CIA and ICV and mass-balance calculations using Grant’s equation and Isocon diagrams, this study systematically investigated the element migration and enrichment patterns as well as the metallogenic mechanism of the area. The results show that the weathering intensity in the study area was generally extremely high: CIA increased rapidly from the limestone stage and approached 100 in the bauxite stage, indicating intense chemical weathering and sustained leaching during ore formation. Element migration exhibited pronounced stage-specific characteristics. During the lateritization stage, Ca, Sr, and Ba, which are associated with carbonate minerals, were strongly depleted, whereas Al and Si were relatively enriched. During the desilicification and aluminum-enrichment stage, SiO2 was intensively leached, Al2O3 was significantly enriched, and key metals such as Li were concentrated. During the purification and enrichment stage, impurity elements were further removed, Al became relatively purified, and associated elements such as Ga, V, and Cr were enriched. Correlation analysis indicates that Li is mainly controlled by clay minerals, Ga is primarily incorporated into aluminosilicate minerals through isomorphic substitution, and REE are jointly controlled by iron–manganese oxides, clay minerals, and the weathering–diagenetic environment. This study suggests that the bauxite mineralization in southeastern Chongqing is essentially the result of carbonate dissolution, clay formation, desilicification and aluminum enrichment, and diagenetic purification driven by an extreme warm and humid climate, providing geochemical constraints for prospecting and resource evaluation of bauxite and associated critical metals in the region.

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雷春生,勾杰,易宗旺,等. 渝东南含铝岩系元素迁移富集规律及成矿过程[J]. 科学技术与工程, , ():

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  • 收稿日期:2026-06-21
  • 最后修改日期:2026-08-18
  • 录用日期:2026-09-09
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