耐湿热环境三氧化钨薄膜制备及氢敏性能研究
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上海电力大学人工智能学部

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TP212

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国家自然科学基金(62205195)


Preparation and Hydrogen Sensing Properties of WO3 Film for Humid and High-Temperature Environments
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Faculty of Artificial Intelligence,Shanghai University of Electric Power

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    摘要:

    在氢气传感领域,三氧化钨(WO3)氢敏薄膜因具备化学稳定性、与氢气反应可逆、高灵敏度、高选择性等优点而被广泛应用。在实际使用中,WO3薄膜存在长期稳定性不强,受高温、高湿环境干扰时氢敏性能下降等问题。为解决上述问题,本研究采用氢氧化钠(NaOH)和3-氨丙基三乙氧基硅烷((3-Aminopropyl)triethoxysilane, APTES)对WO3薄膜进行改性,增强WO3薄膜在高温时与玻璃基片的结合力并提供更多反应位点,使薄膜在高温环境下能保持较好的氢敏性能;在WO3薄膜表面旋涂疏水的2-甲基咪唑锌盐(zeolitic imidazolate framework, ZIF-8)提升薄膜在高湿度环境下的氢敏性能。实验结果表明,薄膜经过浓度为15 %的APTES和2.0 mg/ml的ZIF-8处理后,在1 %氢气浓度下,改性后的薄膜经15次连续测试,平均灵敏度达86.01 %,平均响应时间42 s,重复性为97.25 %。相比于未改性的薄膜,改性薄膜在100 ℃高温环境下能保持较好的氢敏性能,放置7天时,灵敏度达57.2 %,响应时间为67 s;在85 %湿度环境存放7天,灵敏度达78.5 %,响应时间为48 s;在空气环境下放置60天,性能无明显劣化。

    Abstract:

    In the field of hydrogen sensing, tungsten trioxide (WO?) hydrogen-sensitive films are widely used due to their advantages such as chemical stability, reversible reaction with hydrogen, high sensitivity, and high selectivity. However, in practical applications, WO? films suffer from issues such as insufficient long-term stability and degraded hydrogen-sensing performance under high-temperature and high-humidity conditions. To address these problems, this study modifies WO? films using sodium hydroxide (NaOH) and 3-aminopropyltriethoxysilane (APTES) to enhance their adhesion to glass substrates at high temperatures and provide more reactive sites, thereby maintaining good hydrogen-sensing performance in high-temperature environments. Additionally, a hydrophobic zeolitic imidazolate framework (ZIF-8) is spin-coated onto the surface of the WO? film to improve its hydrogen-sensing performance in high-humidity environments. The experimental results show that after the film is treated with 15 % APTES and 2.0 mg/mL ZIF-8, under 1% hydrogen concentration, the modified film exhibits an average sensitivity of 86.01 %, an average response time of 42 s, and a repeatability of 97.25 % after 15 consecutive tests. Compared with the unmodified film, the modified film can maintain favorable hydrogen sensing performance at a high temperature of 100 ℃. After being stored for 7 days, its sensitivity reaches 57.2 % and the response time is 67 s. After being stored in an environment with 85 % humidity for 7 days, the sensitivity is 78.5 % and the response time is 48 s. No obvious performance degradation is observed after being placed in air for 60 days.

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马帷韬,初凤红,胡安铎,等. 耐湿热环境三氧化钨薄膜制备及氢敏性能研究[J]. 科学技术与工程, , ():

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  • 收稿日期:2025-12-23
  • 最后修改日期:2026-04-14
  • 录用日期:2026-04-21
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