泡水对低碳材料固化高浓度铜污染土安全性的影响
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TU526

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国家自然科学基金项目(面上项目,重点项目,重大项目);山西省基础研究计划项目;山西省高等学校科技创新项目;


Influence of Soaking on the Safety Performance of High-concentration Copper-contaminated Soil Solidified by Low-carbon Material
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    摘要:

    聚焦工业固废堆积及重金属污染土两大问题,旨在探究低碳型固化剂用于处理 1% 铜污染土 的 固 化 效 果 及 内 在 机 理。 对比分析固化土中铜离子浸出浓度及形态的改变,检测固化土力学性能及微观结构的变化。 数据表明,固化土在泡水后 的铜离子浓度满足环境安全要求,且重金属由碳酸盐结合态向铁锰氧化态转变。 固化土中可交换态和残渣态占比基本未发 生改变,但其含量有所不同。 此外,泡水对固化土早期强度有明显提升作用,促进了早期水化反应的进行。 微观结果表明,泡 水养护促使固化土中生成了明显的胶凝物质及针状物质。 傅里叶变换红外光谱仪(Fourier transform infrared spectrometer,FT- IR)结果显示,固化土中存在 O—H、CO32 - 及 Si—O / Al—O 基团的存在,综合分析固化土中有碳酸钙及水化硅酸钙等常规水化 产物,同时在磷石膏的作用下有钙矾石的 形 成。 由 此 对 土 中 孔 隙 进 行 有 效 填 充,且 将 重 金 属 离 子 较 好 的 包 裹 吸 附 在 生 成 物 中,致使重金属的浸出浓度满足要求,同时使固化土强度提高。 研究成果为工业固废的有效利用提供了新途径,同时为重金 属污染土的治理提供了一种低碳、经济、有效的固化剂,具有重要的环境、经济和社会效益。

    Abstract:

    Focusing on the two major problems of industrial solid waste accumulation and heavy metal contaminated soil, to explore the solidification effect and internal mechanism of a low-carbon curing agent used for treating 1% copper-contaminated soil. The changes in leaching concentration of copper ions and heavy metal forms in solidified soil were compared and analyzed. Meanwhile, the changes in the mechanical properties and microstructure of solidified soil were detected. The data indicates that the copper ion concentration of solidified soil after soaking complies with environmental safety requirements, and heavy metals transitioned from carbonate-bound state to iron-manganese oxidized state. The proportion of exchangeable and residual states in solidified soil do not change significantly, but their contents are different. In addition, soaking has a significant effect on improving the early strength of solidified soil and promoting the early hydration reaction. Microscopic results indicate that water curing promotes the formation of significant cementitious and needle-like substances in the solidified soil. The Fourier transform infrared spectrometer ( FTIR) results show that the presence of O—H, CO32 - , and Si— O / Al—O groups in the solidified soil. Comprehensive analysis shows the presence of conventional hydration products such as calcium carbonate and hydrated calcium silicate in the solidified soil, as well as the formation of ettringite under the action of phosphogypsum. As a result, the pores in the soil are effectively filled, and heavy metal ions are well encapsulated and adsorbed in the product, resulting in a leaching concentration of heavy metals that meet the requirements, while also promoting the strength of the solidified soil. The reasearch results provide a new approach for industrial solid waste, as well as a low-carbon and effective solidifier for the treatment of copper- contaminated soil, which has important environmental, economic, and social benefits.

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索崇娴,董晓强,独传鑫,等. 泡水对低碳材料固化高浓度铜污染土安全性的影响[J]. 科学技术与工程, 2026, 26(20): 8464-8471.
Suo Chongxian, Dong Xiaoqiang, Du Chuanxin, et al. Influence of Soaking on the Safety Performance of High-concentration Copper-contaminated Soil Solidified by Low-carbon Material[J]. Science Technology and Engineering,2026,26(20):8464-8471.

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  • 收稿日期:2025-07-25
  • 最后修改日期:2026-05-20
  • 录用日期:2026-01-09
  • 在线发布日期: 2026-07-27
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