In order to enhance the de-icing efficiency of cement concrete pavement, wave-absorbing and hydrophobic coatings were prepared in this paper, on the basis of which eight different surface textures were constructed for exploring the effects of surface textures and wave-absorbing materials on microwave warming performance. Firstly, a cement-based coating with both hydrophobic and wave-absorbing properties was prepared by adding nano SiO2; the Mean Texture Depth (MTD) of the different textures was obtained by improving the sand-laying method through machine learning; in order to evaluate the effect of MTD on the microwave warming efficiency and homogeneity, a microwave de-icing vehicle, which is self-developed by the group, was used to carry out a microwave heating test; at the same time, common and ordinary surface textures were tested. In order to evaluate the effect of MTD on microwave warming efficiency and uniformity, the microwave de-icing vehicle developed by the group was used to carry out microwave warming test; at the same time, the Water Contact Angle (WCA) of ordinary and coated concrete surfaces was tested, and ice-concrete ice adhesion shear test was carried out, which was used for evaluating the de-icing effect of coatings prepared in this paper. Finally, in order to ensure the anti-slip performance of the coating designed in this study, the surface anti-slip pendulum value test was also carried out. The results show that the coupling of texture and wave-absorbing coating enhances the wave-absorbing heating efficiency of cement pavement with different degrees of texture, but the texture has a negative effect on the heating uniformity; when the MTD is increased from 0.41 mm (untreated surface) to 2.11 mm, the wave-absorbing heating efficiency of wave-absorbing coated specimens is increased by 1.42 times. At the same time, the coating also significantly enhanced the contact angle of the specimen surface, and the WCA increased from 25.5° to 104°, which in turn reduced the ice adhesion strength. When the design thickness is 1.5 mm, the coating still has good wave-absorbing properties while satisfying the slip resistance.