饱水混凝土中硫酸根离子扩散-反应模型研究
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TU528.01

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Research on Diffusion-Reaction Model of Sulfate Ion in Water-saturated Concrete
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    摘要:

    针对硫酸盐环境下混凝土的劣化问题,本文从腐蚀机理出发,采用Fick第二定律,考虑硫酸根离子在混凝土中扩散的曲折度,结合水泥水化、腐蚀产物填充和材料损伤度对孔隙的影响建立了硫酸盐侵蚀下混凝土的扩散-反应模型;开展了3种水灰比的混凝土在2种浓度的硫酸盐侵蚀条件下的浸泡腐蚀试验,并与模型计算结果对比分析。结果表明:模型计算值与试验实测值基本一致;相同浓度下,水灰比越大混凝土内部同一截面硫酸根离子含量越高;水灰比一样的混凝土,侵蚀浓度越高腐蚀产物填充孔隙周期越短,相同周期内侵蚀深度越大。最后通过建立的混凝土受硫酸根离子侵蚀的最大深度预测模型,可见硫酸盐侵蚀混凝土的最大侵蚀深度随着侵蚀龄期的延长而逐渐变缓,后随着腐蚀产物对混凝土产生损伤,扩散速率加快,侵蚀深度变大。

    Abstract:

    Deterioration of Concrete in Sulfate Environment. Based on the corrosion mechanism, this paper adopts Fick's second law, considers the tortuosity of sulfate ion diffusion in concrete, and combines the effects of cement hydration, corrosion product filling and material damage function on pores to establish the diffusion of sulfate eroded concrete- reaction model. Soaking corrosion tests of concrete with three water-cement ratios under two concentration of sulfate attack were carried out and compared with model calculation results. The results show that the calculated value of the model is basically consistent with the measured value of the test. At the same concentration, the higher the water-cement ratio, the higher the content of sulfate ions in the same section of concrete. The higher the erosion concentration, the shorter the filling period of corrosion products and the greater the erosion depth in the same period. Finally, the maximum depth of concrete eroded by sulfate ions is predicted. It is found that the maximum erosion depth of concrete corroded by sulfate gradually slows down with the prolongation of corrosion age. Then, with the loss of corrosion products to concrete, the diffusion rate increases and the erosion depth increases.

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任青阳,任小坤,靳红华,等. 饱水混凝土中硫酸根离子扩散-反应模型研究[J]. 科学技术与工程, 2023, 23(20): 8804-8811.
Ren Qingyang, Ren Xiaokun, Jin Honghua, et al. Research on Diffusion-Reaction Model of Sulfate Ion in Water-saturated Concrete[J]. Science Technology and Engineering,2023,23(20):8804-8811.

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  • 收稿日期:2022-07-12
  • 最后修改日期:2023-04-17
  • 录用日期:2022-12-26
  • 在线发布日期: 2023-07-24
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